Organic metal (EDO-TTF)2PF6with multi-instability

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Organic metal (EDO-TTF)2PF6 with multi-instability.

The multi-instability of the electronic structure of (EDO-TTF)2PF6, where EDO-TTF means ethylene-dioxytetrathiafulvalene, is reviewed. This complex showed the metal-insulator transition at 280 K associated with distinct molecular deformations. The mechanism is interpreted as the cooperation of Peierls transition, charge ordering, and the order-disorder transition of the countercomponent. The ch...

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Department of Materials Science and Engin Michigan 48109, USA. E-mail: jinsang@um Department of Chemical Engineering, Univ 48109, USA Macromolecular Science and Engineering Michigan 48109, USA Department of Biointerface Institute, Univ 48109, USA Department of Chemistry, University of Mic Materials and Process R&BD Group, Ko (KITECH), South Korea Madrid Institute for Advanced Studies – IMD Univ...

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ژورنال

عنوان ژورنال: Science and Technology of Advanced Materials

سال: 2009

ISSN: 1468-6996,1878-5514

DOI: 10.1088/1468-6996/10/2/024305